New thermoplastic poly(carbonate-urethane) elastomers

Synthesis of bio-based thermoplastic polyurethane elastomers containing isosorbide and polycarbonate diol and their biocompatible properties.

A new family of highly elastic polyurethanes (PUs) partially based on renewable isosorbide were prepared by reacting hexamethylene diisocyanate with a various ratios of isosorbide and polycarbonate diol 2000 (PCD) via a one-step bulk condensation polymerization without catalyst. The influence of the isorsorbide/PCD ratio on the properties of the PU was evaluated. The successful synthesis of the...

Electroactive Thermoplastic Dielectric Elastomers as a New Generation Polymer Actuators

Thermoplastic Elastomers with Photo-actuating Properties

This contribution reviews elastomeric materials with photo-actuation behavior with emphasis on thermoplastic elastomers and their composites. The principles of the photo-actuation and the main factors affecting the photo-actuation phenomena of thermoplastic elastomer materials are discussed in detail. The well-performing photoactuating systems involving both statistical and block copolymers-bas...

Synthesis of polycarbonate urethane elastomers and effects of the chemical structures on their thermal, mechanical and biocompatibility properties

In this study, to obtain biomedical polyurethane elastomers with good mechanical properties and biocompatibility, a series of polycarbonate urethanes were synthesized via a two-step solution of polymerization method using the poly(1,6-hexanediol)carbonate diols (PCDL) as the soft segment, 4,4'-methylenebis(cyclohexyl isocyanate) (H12MDI), 1,6-hexamethylene diisocyanate (HDI) and 1,4-butanediol ...

Development of biodegradable crosslinked urethane-doped polyester elastomers.

Traditional crosslinked polyester elastomers are inherently weak, and the strategy of increasing crosslink density to improve their mechanical properties makes them brittle materials. Biodegradable polyurethanes, although strong and elastic, do not fare well in dynamic environments due to the onset of permanent deformation. The design and development of a soft, strong and completely elastic (10...